Spray a 9 x 13 inch baking dish with cooking spray.: The dish will smell faintly of oil as you coat it, and the slick surface helps the caramel release when serving. Greasing is crucial so the sticky caramel does not bond permanently to the pan, making serving difficult. A common mistake is skimping on the spray which can cause the caramel to stick and tear the slices, so be thorough when coating the entire interior.
Combine brown sugar, corn syrup and butter in a small saucepan. Cook over medium heat for 5 minutes or until mixture is bubbly, stirring constantly. Pour mixture evenly into prepared pan.: As the mixture warms you will notice the brown sugar dissolving and the surface turning glossy, while the butter melts into a fragrant, slightly toasty aroma. Constant stirring prevents scorching and encourages even melting, producing a smooth, syrupy texture ready to coat the pan. If the heat is too high the sugars can darken quickly and develop a bitter edge, so keep it at a steady medium and watch closely for an evenly bubbling sheen.
Arrange the bread slices in a single layer over the syrup in the dish. Combine milk and next 4 ingredients (through eggs) in a large bowl, stirring with a whisk. Pour egg mixture over bread slices. Cover and refrigerate for 8 hours or overnight.: When you place the French bread over the warm caramel, it will begin to absorb some of the syrup, producing a glossy underside that will deepen in flavor overnight. Mixing the milk , all purpose flour , vanilla extract , salt , and eggs creates a smooth custard that smells sweet and slightly eggy when whisked. Pouring the custard slowly allows the bread to soak uniformly, and covering it for refrigeration lets the custard firm up gently. Avoid pouring too quickly which can cause displacement of the bread and uneven soaking, and be patient with the overnight rest for best texture.
When ready to cook, preheat oven to 350°F.: The oven gives off a warm, dry heat and the preheat step ensures even baking. Allowing the oven to fully reach 350°F yields predictable browning and a consistent set for the custard. A premature insertion into a still warming oven can lead to uneven texture and longer cook times, so confirm the temperature before sliding the dish in.
Combine sugar and cinnamon. Sprinkle evenly over bread.: The blend of granulated white sugar and ground cinnamon dusted across the top will smell warmly spiced and provide a delicate, sugary crust as the bake progresses. Even sprinkling ensures every slice gets a touch of sweet spice without clumping. One error to avoid is over applying the topping in one concentrated area which can create overly sweet pockets and uneven browning.
Bake for 50 minutes or until golden. Let stand for 5 minutes before serving.: As the dish bakes you will hear a gentle sigh from the oven and notice the edges bubbling slightly where the caramel meets the glass. The top should turn a warm golden color and the center should feel set but still springy, giving a custardy bite rather than a runny puddle. Letting it rest for 5 minutes allows the caramel to cool slightly and thicken, making slicing cleaner and presentation neater. A common pitfall is cutting too soon which can cause the custard to slump, so give it the brief rest it needs.