Prep pans: Preheat oven to 350 degrees F. Line the bottom of two 9'' round baking pans with a piece of parchment paper and lightly spray all over the inside of the pan with nonstick cooking spray. Set aside.: The warm scent of a kitchen preparing to bake is comforting, and you will notice a faint warmth from the oven when you open it; this readiness prevents temperature drop when the batter goes in. Ensuring parchment is cut and fitted prevents sticking and makes unmolding simple, which preserves the cake edges and appearance. One common mistake is not spraying the sides after the parchment is placed, leading to cakes sticking along the rim, so be thorough with a light coating. Also, check the oven rack is centered for even rise. Proper pan prep reduces tearing when you invert the cakes, and it shortens cleanup time.
Sift all-purpose flour and cake flour into a mixing bowl. Add baking powder, baking soda, and salt then stir to combine.: When you sift and blend these dry ingredients you create a uniform matrix so the leaveners are evenly distributed, which helps the cake rise uniformly and prevents pockets of baking powder. The mixture should look light and aerated, with a soft, almost powdery feel under your fingers. A common error is skipping sifting and getting uneven rise or small lumps of leavening, so take the extra minute to whisk thoroughly. Even distribution also helps flavor balance, so every bite gets the correct lift and tenderness.
In a separate mixing bowl, add the butter, sugar and lemon zest then mix with an electric mixer until pale and fluffy, about 3-4 minutes. Add the whole eggs and mix well. Add the egg whites one at a time, mixing after each. Stir in the vanilla.: Creaming butter and granulated sugar releases air, producing a lighter texture; you will see the color shift to a pale yellow and notice a soft, billowy texture. Adding the lemon zest while creaming integrates citrus oils for aromatic lift. When you incorporate the eggs , add them gradually so the batter does not break; it should remain glossy and cohesive. A frequent mistake is adding eggs too quickly, causing a curdled appearance, but gentle mixing brings it back together. The aroma of citrus and sweet butter will be strong and inviting, which is a good sign you are on track.
Alternately add in a little bit of the flour mixture and then the buttermilk, stirring between each addition. Divide batter evenly between the two prepared round cake pans.: Alternating dry and wet additions prevents overmixing and helps maintain a tender crumb; the batter should feel smooth and slightly thick, not dense. When pouring into pans, the batter's surface should be level and glossy; tapping the pans lightly on the counter removes air bubbles and encourages even settling. A typical slip is dumping all the flour at once, which can lead to a tough cake from overworked gluten, so be patient with the alternation. Weighing or visually dividing batter helps produce two cakes of equal height for easier stacking and frosting.
Bake in preheated oven until toothpick inserted into center of the cakes comes out clean, about 24-29 minutes. Remove from oven and allow to cool several minutes in the pans, then transfer to a wire rack to cool completely.: During baking you will smell the lemon and butter deepen and see the edges pull slightly away from the pan as a visual cue of doneness; the top should be a pale golden tone. The toothpick test should yield a few moist crumbs, not wet batter. Letting the cakes rest in their pans for a few minutes allows structure to set, preventing collapse when inverted. A common mistake is leaving them in the pan too long, which can trap steam and make the bottom soggy, so use a timer and then move to a wire rack promptly.
Add butter to a stand mixer or large mixing bowl and beat with beaters for 1 minute. Add 4 cups of powdered sugar, half of the lemon juice and the lemon zest. Beat well until smooth and creamy, about 3 minutes.: The first step of the frosting is about texture, not speed; soft butter beaten briefly becomes silky and ready to incorporate the sugar without lumps. When you add the initial portion of powdered sugar and lemon juice , the mixture will thicken and smell brightly citrusy, with a glossy sheen. If the frosting seems gritty, beat longer or sieve the sugar before adding. A typical pitfall is using cold butter, resulting in a lumpy frosting, so ensure the butter is room temperature for smoothness.
Gradually add the remaining sugar, 1 cup at a time, and the remaining lemon juice until you reach your desired frosting consistency. Add more juice to thin, or more sugar to thicken.: Building the frosting slowly allows precise control over consistency and sweetness; as you add each cup of powdered sugar the frosting will firm up and the lemon aroma will intensify. Taste as you go so the balance of sweet and tart sits where you want it. A common misstep is adding all the juice at once which can make the frosting too thin and runny; if that happens, add more sugar and chill briefly to firm it back up. The final frosting should be silky, spreadable, and bright with citrus notes.
Frost cake once the cake is completely cool.: Cooling completely is crucial so the frosting does not melt and slide off, you will notice a warm cake will steam slightly when frosted, which indicates it is too hot. When the layers are cool, the frosting spreads smoothly and holds any decorations or piping you choose. Avoid the temptation to frost warm layers, as this causes sliding and a thin, translucent coat; patience at this step preserves the cake's look and texture. Once frosted the cake will have a creamy exterior and a fragrant lemon finish that complements the tender crumb.