Fill a medium bowl with just 1 teaspoon of salt, ice and water. Add the shrimp and let soak for 15 minutes. While brining, proceed to next step to make crispy basil.: The moment the shrimp hits the cold salty bath you will notice the water take on a faint sweet scent, as the brine firms the flesh and draws out impurities. This short soak tightens the texture so the shrimp sears instead of collapsing, and it also seasons through. A common mistake is over brining, which will make the shrimp overly salty and mealy, so stick to the fifteen minute window. After draining, pat thoroughly with paper towels, because any lingering water will steam the shrimp in the pan and prevent the desired crisp edges.
To make the crispy basil: Wash and pat very dry the basil leaves. The leaves MUST be very dry, or the oil will splatter. Add 4 tablespoons cooking oil to the wok or a small saute pan. When the oil is hot and shimmering (but not smoking quite yet), add in a single basil leaf to test. Deep fry the basil leaves in batches, and letting them cool on a plate with paper towels to absorb the excess oil.: Wash and pat very dry the basil leaves. The leaves MUST be very dry, or the oil will splatter. Add 4 tablespoons cooking oil to the wok or a small saute pan. When the oil is hot and shimmering (but not smoking quite yet), add in a single basil leaf to test. Deep fry the basil leaves in batches, and letting them cool on a plate with paper towels to absorb the excess oil. : When you fry the first leaf you will hear a rapid, light crackle and see it immediately change color and texture, becoming almost translucent. That sound and sight tell you the oil is at the right temperature. Fry in small batches so the oil temperature does not plunge, otherwise the leaves will become greasy rather than crisp. Use tongs or a spider to lower leaves gently and remove them once they crisp in a few seconds. A frequent error is crowding the pan, which traps steam and yields limp herbs; so work in quick successive batches and blot on paper towels to drain excess oil.
Back to the brining shrimp…. Drain and pat very dry on paper towels. Empty the bowl, wipe the bowl dry and return the shrimp, the remaining 1/4 teaspoon salt, sesame oil and cornstarch. Stir to coat the shrimp.: After the brine step, drying the shrimp is essential because moisture prevents browning. Tossing with the cornstarch gives each piece a subtle velvety layer that crisps when it meets the hot oil, while the sesame oil brings aromatic depth. Stir just until evenly coated; overcoating makes a gummy crust, so err on the lighter side. If pieces feel tacky, they are ready to sear—too much cornstarch will clump during cooking, so measure carefully.
Heat a wok or large saute pan over high heat until a bead of water sizzles and evaporates on contact. Add the cooking oil, swirling to coat the wok. Add the shrimp and immediately give each shrimp its own space on the wok, so that they aren't touching. Let fry, untouched for 1 minute. Flip shrimp and let fry for an additional minute, or just cooked through. Remove from wok, leaving as much oil in wok as possible.: When you test with a water bead, listen for a rapid sizzle and watch it vanish instantly; that tells you the pan is hot enough. Giving each shrimp space ensures even searing and prevents steaming, which is why I let them sit untouched to form a golden crust. The sound will change to a firmer sizzle as the crust forms. Flipping once preserves juiciness. Avoid overcooking here since shrimp will toughen quickly; they are done when opaque and slightly firm to the touch. Transfer them to a plate to rest briefly so they do not continue to cook in the pan.
You should still have 1 tablespoon of cooking oil in the wok. If not, add more cooking oil. Return the heat to medium-high and let the oil heat up. Add in the chili pepper and garlic and fry until fragrant, about 15 seconds. Add in the zucchini slices and stir fry for 1-2 minutes, tossing every 15 seconds, until zucchini is just barely soft in the middle but still firm on the outer edge.: The moment the garlic hits the hot oil the kitchen will fill with a warm, toasty aroma, but it browns extremely fast so watch it closely. Quick tossing keeps the zucchini cooking evenly, producing a tender center and a slightly seared exterior. Listen for a lively sizzle that signals the pan is doing its job. If you let the garlic burn, it will taste bitter and ruin the dish, so reduce heat immediately if you see dark flecks. Keep the vegetable pieces similar in thickness so they finish uniformly.
Pour in the stir fry sauce to the wok. Add back into wok the cooked shrimp. Toss everything together to allow the sauce to coat the shrimp and the zucchini. Top the dish with crispy basil.: As the sauce hits the hot wok it should bubble and thicken slightly, coating the zucchini and shrimp with a glossy sheen. Tossing quickly ensures every piece picks up flavor and the sauce reduces just enough to cling without pooling. You will notice an instant gloss and a soft hiss as moisture evaporates, concentrating flavor. A common slip is adding the sauce too early, which can steam the ingredients and leave the liquid thin, so bring the sauce in at this finishing stage. Finish by scattering the fried basil on top so it stays crisp and adds that final aromatic pop.