To a large zip top bag, add the olive oil, balsamic vinegar, Italian seasoning, onion flakes, salt, pepper, chicken, tomatoes, zucchini, peppers, seal bag, and squish everything around to combine.: The aroma of olive oil and balsamic vinegar mingling with herbs is immediate and inviting, and you should notice the glossy coating on the chicken and vegetables once massaged. This tactile step helps the seasoning penetrate surfaces, and squishing ensures even coverage. Watch for pooled liquid at the bottom of the bag, which indicates good contact, but avoid overhandling which can bruise delicate tomatoes . A common mistake is using too small a bag, which prevents thorough mixing and leaves some pieces underseasoned.
Place bag in fridge to marinate for at least 30 minutes and longer if you have time. I marinated overnight.: As the mixture chills, the balsamic vinegar gently tenderizes the chicken and the flavors meld into the vegetables . Overnight gives the most developed taste, while 30 minutes still imparts noticeable flavor. You should feel the marinade slightly cling to the protein when you take it out; that is a good visual cue. Avoid marinating too long with highly acidic marinades for very thin pieces of chicken , which can make the texture mushy.
Preheat oven to 425 F, line a baking sheet with aluminum foil for easier cleanup, and spray with cooking spray.: The oven’s heat is what creates those golden edges, and setting it to 425 F gives a lively roast without drying the chicken . Lining the pan helps transfer from oven to table and keeps cleanup quick, and a light spray prevents sticking. You should hear a subtle sizzle when the pan goes in, which is a satisfying sound that means caramelization is starting. Do not use a crowded pan or a low temperature, which will produce steamed, pale vegetables instead of roasted ones.
Using a slotted spoon, remove the chicken and vegetables from the bag and place them in an even, flat layer on baking sheet.: As you transfer, let excess marinade drip back into the bag to prevent pooling on the sheet, which can cause sogginess. Arrange the pieces so nothing overlaps, giving each item room to brown. Visual cues to aim for include a single layer with pieces not touching too much, and varied spacing so hot air circulates. A mistake I see often is crowding the pan, which leads to uneven cooking and lackluster browning.
Bake for about 25 to 30 minutes or until chicken is cooked through (internal temp of 165 F) and vegetables are tender. Flip chicken and toss vegetables halfway through baking to ensure even cooking. Cooking time will vary based on how thick your chicken is.: During roasting you will notice the edges crisping and the vegetables beginning to collapse slightly as their sugars caramelize. Flip and toss at the halfway point so both sides get those golden notes and the aromatics concentrate. Use an instant read thermometer to check that the chicken reaches 165 F, and look for tender, blistered tomatoes and peppers with charred bits. Avoid overbaking, which dries the chicken and makes zucchini too soft.
Optionally, evenly sprinkle with Parmesan, basil, and drizzle with balsamic glaze before serving.: The final garnishes add layers of texture and brightness, the salty Parmesan cheese melting slightly on hot pieces, and fresh basil releasing perfume as it warms. A light drizzle of glaze glistens and ties flavors together. Add these touches at the end so they keep their visual and aromatic impact. A common misstep is adding cheese too early, which can burn and become bitter instead of nutty and melty.