Heat a grill or grill pan to medium-high heat and lightly rub your grill with olive oil.: You will immediately notice the faint, metallic hiss as the metal heats, and when the grill reaches the correct temperature it gives off a dry warmth that crisps surfaces quickly. Heating to medium high ensures the polenta gets nice sear marks without needing excessive time that would dry the interior. Rubbing the grill with olive oil creates a thin nonstick layer, preventing sticking and promoting even browning. If your grill is too cool the polenta will warm slowly and stick, and if it is too hot the outside can char before the center warms. A common mistake is skipping the oil which leads to tearing when you flip the pieces.
Brush both sides of the polenta cakes with the olive oil. Sprinkle both sides with parmesan, salt and pepper.: As you brush each round, the oil will glisten on the surface and help the parmesan adhere. The oil also helps create a toasty, golden crust by transmitting heat and encouraging the Maillard reaction. Work quickly so the oil does not pool, and apply a thin, even coat for consistent results. Smell the oil warm slightly as it meets the heated surface and expect a subtle fruity aroma. Overbrushing can cause flare ups and greasy patches, so avoid excess.
Lay the polenta rounds in one layer on the grill, and grill for 5 minutes on each side or until both sides are golden and crunchy and have grill marks.: When you dust the grated parmesan onto the oiled rounds, the cheese clings and forms a textured layer that browns beautifully on the grill. The salt and pepper season through to the center as the pieces warm, balancing the corn flavor. Press the cheese lightly so it sticks, and take note of the grainy look as it readies to melt then toast. If cheese is too loosely applied it may fall through grill grates or burn quickly, producing a bitter taste.
Remove the cakes from the grill and place on a large plate to cool. Serve warm or at room temperature. I love serving these with blue cheese, salsa or guacamole or simply snacking on them plain!: As the rounds meet the hot metal you will hear a soft sizzle that signals exterior moisture evaporating and the crust forming. After the first few minutes lift a corner to check for a deep golden color and clear grill marks, then flip carefully with tongs to avoid splintering. The aroma will shift to toasted cheese and warm corn, and the surface should feel firmer when touched. If you try to flip too early they will stick and tear, and if you leave them too long the cheese may blacken. Aim for evenly golden surfaces that are crunchy to the touch.
Remove the cakes from the grill and place on a large plate to cool: Pull the chips off when they are uniformly golden and give them a moment to set; the exterior crisps further as they rest, while the center retains creamy texture. Arrange them on a plate so air circulates and they don’t steam each other. The warm, nutty perfume of toasted parmesan will be most pronounced right away, and cooling slightly makes them easier to handle. A pitfall is stacking them while very hot, which traps steam and softens the crust, so spread them out instead.
Serve warm or at room temperature: These chips are convivial because they work hot or cooled, and the flavor shifts subtly as they sit, with the cheese note mellowing and the texture holding firm. I often offer small spoons of gorgonzola , salsa, or guacamole for dipping, which adds contrast to the savory crispness. If you refrigerate leftovers, reheat briefly on a grill pan to restore crunch. Do not microwave if you want to keep the crisp texture, as that tends to make them gummy.