Preheat the oven to 450°F (230°C) and set an oven rack in the middle position.: Before you begin, make sure the oven is fully heated so the tray will start caramelizing the moment it goes in. You should feel warm air when you open the oven and see that the racks are centered, which ensures even heat circulation. The intense heat produces those beautifully browned, crisp edges we want. A common mistake is not preheating long enough, which can lead to longer cook times and less crispness.
In a large pot, bring 3 quarts (3 L) of water to a boil. Stir in 1 tablespoon of salt and the baking soda. Add the potatoes and boil for 10 minutes. Drain the potatoes thoroughly.: The sound of a lively boil signals it's time to season the water, and the visual cue is steady rolling bubbles across the surface. Using a large pot keeps the temperature from dropping too much when you add the sweet potatoes . If the pot is too small, the water temperature will fall and the par boil will take longer, which affects texture.
Directly on a rimmed baking sheet (avoid using foil as the potatoes may stick), toss the par-boiled potatoes with the potato starch, oil, 1/2 teaspoon of salt, half of the rosemary, and the pepper. Roast in the preheated oven for 35 minutes, stirring once midway through roasting. After roasting, turn off the oven but leave the potatoes inside for an additional 10 to 15 minutes.: Dissolve the salt and baking soda so they can act on the surface of the sweet potatoes . The baking soda slightly raises the pH, helping the exterior break down and develop more surface roughness for crisping. You will notice the water looks a touch more active with the soda added. Be careful with the soda quantity because excess will cause the potatoes to become mushy.
Remove from the oven and sprinkle with the remaining rosemary. Taste and adjust the seasoning with salt, if necessary. Transfer the sweet potatoes to a platter and serve.: When the sweet potatoes hit the boiling water, you will hear a gentle chatter as the water returns to a boil. After roughly 10 minutes, the edges should give slightly when pierced with a knife, indicating they are par boiled and not fully falling apart. This step softens the interior while keeping the exterior intact, which is crucial for the final texture. Over boiling is a common pitfall that results in disintegrated pieces during roasting.
Drain the potatoes thoroughly: After pouring off the water, shake the colander a few times to get rid of excess moisture. The sound is a quick clatter as the water drains away, and the surface should look matte rather than wet. Excess water prevents the potato starch from adhering properly and will hinder browning, so thorough draining is essential.
Directly on a rimmed baking sheet toss the par boiled potatoes with the potato starch, oil, 1/2 teaspoon of salt, half of the rosemary, and the pepper: As you toss, you will see a powdery dusting of potato starch turn into a slightly tacky surface as the olive oil clings to the pieces. This mixture is what creates the crisp exterior and golden color when roasted. Distribute the coating evenly so no piece is left bare, because uneven coating causes patchy browning. Avoid using foil because it can trap moisture and promote sticking.
Roast in the preheated oven for 35 minutes stirring once midway through roasting: When the tray goes in, you should hear a faint hiss as the oil heats and the sugars begin to brown. At around the halfway mark, use a spatula to turn the pieces so multiple sides get direct contact with the hot sheet, revealing a deeper golden color. The aroma will shift from a soft sweet scent to a richer, toasty fragrance. A frequent misstep is stirring too often, which prevents the surface from forming a proper crust.
After roasting, turn off the oven but leave the potatoes inside for an additional 10 to 15 minutes: With the oven off, the residual heat continues to dry and set the crust without over browning. The quiet warmth helps the interior settle and the exterior firms up further, and you may notice a concentrated roasted scent as they rest. Removing them immediately can sometimes leave centers too soft, so patience here improves texture.
Remove from the oven and sprinkle with the remaining rosemary: The act of scattering fresh rosemary releases an herbal perfume that brightens the roasted aroma. The contrast between the hot potatoes and the fresh herb is immediate, creating a lively final note. Be mindful that adding herbs earlier can cause them to become woody, so reserve some for this finishing touch.
Taste and adjust the seasoning with salt, if necessary: A small taste will reveal if the dish needs a final pinch of salt . The boiled potatoes absorb seasoning differently, so checking at the end ensures balance. Over salting is easy to do, so add sparingly and taste after each small adjustment.
Transfer the sweet potatoes to a platter and serve: The final presentation should show deeply browned edges and an inviting sheen from the oil. Serve while warm so the contrast of textures is most pronounced. If you let them sit too long, the crispness will fade, so plan the timing so they hit the table shortly after plating.